I’have tries these.

`Transpose[CharacterRange["A", "F"], CirclePoints[6]] `

But this seemed not to work.

I want this output below.

`{{"A",{1/2, -(Sqrt[3]/2)}},{"B", {1, 0}}, {"C",{1/2, Sqrt[3]/2}}, {"D",{-(1/2), Sqrt[3]/ 2}}, {"E",{-1, 0}}, {"F",{-(1/2), -(Sqrt[3]/2)}}} `