I’have tries these.
Transpose[CharacterRange["A", "F"], CirclePoints[6]]
But this seemed not to work.
I want this output below.
{{"A",{1/2, -(Sqrt[3]/2)}},{"B", {1, 0}}, {"C",{1/2, Sqrt[3]/2}}, {"D",{-(1/2), Sqrt[3]/ 2}}, {"E",{-1, 0}}, {"F",{-(1/2), -(Sqrt[3]/2)}}}